Reaction Kinetics in Restricted Spaces
نویسندگان
چکیده
منابع مشابه
Reaction Kinetics in Restricted Spaces
Reactions in restricted spaces rarely get stirred vigorously by convection and are thus controlled by diffusion. Furthermore, the compactness of the Brownian motion leads to both anomalous diffusion and anomalous reaction kinetics. Elementary binary reactions of the type A + A + Products, A + B + Products, and A + C + C + Products are discussed theoretically for both batch and steady-state cond...
متن کاملReaction Kinetics in Polymer Melts
We study the reaction kinetics of end-functionalized polymer chains dispersed in an unreactive polymer melt. Starting from an infinite hierarchy of coupled equations for many-chain correlation functions, a closed equation is derived for the 2nd order rate constant k after postulating simple physical bounds. Our results generalize previous 2-chain treatments (valid in dilute reactants limit) by ...
متن کاملClosure spaces and restricted games
We study a cooperation structure in which the feasible coalitions are those belonging to a partition closure system. First, we develop the relation between the dividends of Harsanyi in the restricted game and the worth function in the original game. Next, we obtain an method for computing the Shapley and Banzhaf values of the closure-restricted games using the dividends formula. Finally, we ana...
متن کاملSpatially Resolved Anomalous Kinetics of a Catalytic Reaction: Enzymatic Glucose Oxidation in Capillary Spaces
A reaction involving the catalytic oxidation of glucose by the enzyme glucose oxidase is employed as a first spatially resolved experimental realization of a nonclassical A + C f C + Products chemical reaction. This heterogeneous kinetics experiment models the operation of optical glucose sensors. One-dimensional nonclassical reaction kinetics, manifested in anomalous rate laws, are observed. T...
متن کاملOn Policy Learning in Restricted Policy Spaces
We consider the problem of policy learning in aMarkov Decision Process (MDP) where only a restricted, limited subset of the full policy space can be used. A MDP consists of a state space S, a set of actions A, a transition probability function t(s, a, s′) and a reward function R : S → R. Also there is the discount factor γ. The problem is to find a policy, a mapping from states to actions π : S...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Israel Journal of Chemistry
سال: 1991
ISSN: 0021-2148
DOI: 10.1002/ijch.199100016